Structure of 1% copper(II)-doped dichlorobis(1,2-dimethylimidazole)zinc(II)

Bharadwaj, P. K. ; Schugar, H. J. ; Potenza, J. A. (1991) Structure of 1% copper(II)-doped dichlorobis(1,2-dimethylimidazole)zinc(II) Acta Crystallographica Section C: Crystal Structure Communications, C47 . pp. 754-757. ISSN 0108-2701

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Official URL: http://scripts.iucr.org/cgi-bin/paper?gr0122

Related URL: http://dx.doi.org/10.1107/S0108270190011726

Abstract

[Zn0.99Cu0.01Cl2(c5H8N2)2], Mr= 328.43, monoclinic, P21/c, a= 13.857(1), b=7.1324(7), c= 16.356 (2) Å, β= 112.87 (1)°, V=1460.4(5) Å3, Z=4, Dm = 1.50(1), Dx= 1.492g cm-3, µ(Mo Kα, λ= 0.71073 Å) = 20.8cm-1, F(000) = 672.0, T=297(1)K, R=0.028 for 1782 unique observed reflections. The structure contains discrete dichloro-bis(1,2- dimethylimidazole)zinc(II) molecules. Pseudotetrahedral N2Cl2 coordination about zinc is effected by coordination to two imidazole.

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Deposited On:18 Oct 2010 06:26
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