Acrylonitrile copolymers using cobalt acetylacetonate-triethylaluminum initiator system. 5. Monomer sequence distributions in acrylonitrile-styrene copolymers

Kalyanam, N. ; Gandhi, V. G. ; Sivaram, S. (1984) Acrylonitrile copolymers using cobalt acetylacetonate-triethylaluminum initiator system. 5. Monomer sequence distributions in acrylonitrile-styrene copolymers Polymer Bulletin, 11 (2). pp. 105-108. ISSN 0170-0839

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Official URL: http://www.springerlink.com/content/k624w1547t8k53...

Related URL: http://dx.doi.org/10.1007/BF00258015

Abstract

The reactivity ratios of styrene and acrylonitrile were computed from the 13C-NMR spectra of copolymers prepared using cobalt acetylacetonate-triethylaluminum initiator system and compared with a free radical initiator such as AIBN. The results indicate that polymerization using the former has pronounced free radical characteristics.

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