Neogi, Subhadip ; Bharadwaj, Parimal K. (2005) An infinite water chain passes through an array of Zn(II) metallocycles built with a podand bearing terminal carboxylates Inorganic Chemistry, 44 (4). pp. 816-818. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic048489a
Related URL: http://dx.doi.org/10.1021/ic048489a
Abstract
A podand bearing three carboxylic acid groups was synthesized by condensation of tris(2-chloroethyl)amine with 4-hydroxyethylbenzoate followed by hydrolysis of the ester group. An aqueous solution of Zn(NO3)2·6H2O reacts with the tetraethylammonium salt of the podand at room temperature, to form a porous coordination polymeric structure with infinite interlinked chains of Zn(II) metallocycles. An infinite water chain passes through the metallocycles like a thread. The compound was characterized by X-ray crystallography, X-ray powder diffraction, TGA, IR spectroscopy, and elemental analysis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 4820 |
| Deposited On: | 18 Oct 2010 06:35 |
| Last Modified: | 18 May 2011 08:17 |
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