High pressure study of pentaerythritol: a synchrotron infrared study

Deb, S. K. ; Banerji, Ankita ; Kshirsagar, R. J. ; Sharma, Surinder M. ; Dumas, P. ; Marin, T. ; Chervin, J. C. ; Canny, B. (2006) High pressure study of pentaerythritol: a synchrotron infrared study Infrared Physics & Technology, 49 (1-2). pp. 82-87. ISSN 1350-4495

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.infrared.2006.01.013

Abstract

High-pressure infrared (IR) absorption study of phase transition in pentaerythritol (PET) is reported. The changes in the IR spectra with increasing and decreasing pressure have been followed up to a maximum pressure of ≈11GPa. We observe several changes in the spectra including splitting of modes and sudden change in the slope of the frequency vs. pressure curve at about 4.7 GPa. The transition has been found to be completely reversible. We interpret these changes in terms of a symmetry lowering phase transition.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Infrared Spectroscopy; Phase Transition; High Pressure; Synchrotron
ID Code:48174
Deposited On:14 Jul 2011 08:29
Last Modified:14 Jul 2011 08:29

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