Quantum mechanical second virial coefficient of a gas with square-well plus hard-core potential

Sinha, S. K. ; Singh, Y. (1977) Quantum mechanical second virial coefficient of a gas with square-well plus hard-core potential Journal of Chemical Physics, 67 (5). pp. 2278-2283. ISSN 0021-9606

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Official URL: http://link.aip.org/link/jcpsa6/v67/i5/p2278/s1

Related URL: http://dx.doi.org/10.1063/1.435062

Abstract

The quantum mechanical second virial coefficient of a gas with square-well plus hard-core potential is evaluated at low and high temperatures. The low temperature result is given in a series in the ascending powers of (a/λ), and the first four coefficients are given. The direct part of the second virial coefficient at high temperature is given in a series in the ascending powers of (λ/a), and the first three coefficients are given. Our result for the first coefficient in the high temperature series is in agreement with the result of previous workers.

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