Virial coefficients of the equation of state of a gas of nonspherical molecules. II. Polar molecules

Singh, S. ; Singh, Y. (1977) Virial coefficients of the equation of state of a gas of nonspherical molecules. II. Polar molecules Physica A: Statistical and Theoretical Physics, 87 (2). pp. 344-353. ISSN 0378-4371

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0378-4371(77)90021-8

Abstract

The second and third virial coefficients of polar gases have been calculated for a set of force parameters which has been found suitable to explain the dilute gas viscosity data. The influence of a large number of orientation dependent pair- and three-body nonadditive interactions have been taken into account. The relative contribution of each branch of pair and triplet interactions has been evaluated as a function of temperature. The theoretical results have been compared with the experimental data of NH3 and CH3F.

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