Neogi, Subhadip ; Savitha, G. ; Bharadwaj, Parimal K. (2004) Structure of discrete (H2O)12 clusters present in the cavity of polymeric interlinked metallocycles of Nd(III) or Gd(III) and a podand ligand Inorganic Chemistry, 43 (13). pp. 3771-3773. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic0495618
Related URL: http://dx.doi.org/10.1021/ic0495618
Abstract
A new podand ligand has been designed and synthesized which reacts hydrothermally with either Nd(III) or Gd(III) nitrate forming an array of linked metallocycles with void spaces. Discrete dodecameric water clusters occupy the voids in the structures. The structure of the cluster can be described as an open-cube octamer buttressed on two sides by dimers to form the overall dodecamer. These clusters join different arrays of linked metallocycles.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 4790 |
| Deposited On: | 18 Oct 2010 06:41 |
| Last Modified: | 18 May 2011 08:23 |
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