Raghavan, P. S. ; Ramaswamy, V. ; Upadhya, T. T. ; Sudalai, A. ; Ramaswamy, A. V. ; Sivasanker, S. (1997) Selective catalytic oxidation of thioethers to sulfoxides over Mo-silicalite-1 (MoS-1) molecular sieves Journal of Molecular Catalysis A: Chemical, 122 (1). pp. 75-80. ISSN 1381-1169
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S1381-1169(97)00019-8
Abstract
Mo-containing silicalite-1 (MFI) samples with Si/Mo (mole) ratios in the range 80 to 300 have been synthesized hydrothermally and were characterized by different physico-chemical techniques such as SEM, XRD, BET, TG/DTA, FTIR, XPS, UV-visible spectra. The catalyst was found to be active for the chemoselective oxidation of various thioethers to the corresponding sulfoxides, without generation of sulfones, using 30% H2O2 as the oxidant.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Mo-MFI; Mo-silicalite; Sulfoxidation; Thioethers; Sulfones |
| ID Code: | 47665 |
| Deposited On: | 12 Jul 2011 14:34 |
| Last Modified: | 12 Jul 2011 14:34 |
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