Aspects of secondary bonding intramolecular interaction in organomercury and organochalcogen derivatives

Sharma, Sagar ; Chakraborthy, Tapash ; Srinivasa, Kriti ; Singh, Harkesh B. (2011) Aspects of secondary bonding intramolecular interaction in organomercury and organochalcogen derivatives Journal of Chemical Sciences, 123 (2). pp. 113-122. ISSN 0253-4134

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Abstract

Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:M-C Bond Cleavage; Metallophilic; Secondary Bonding Intramolecular Interaction; Organochalcogen; Telluroxane; Transmetallation
ID Code:47632
Deposited On:11 Jul 2011 13:48
Last Modified:18 May 2016 03:12

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