Intramolecular Se···N nonbonding interactions in low-valent organoselenium derivatives: a detailed study by 1H and 77Se NMR spectroscopy and X-ray crystallography

Mugesh, G. ; Panda, Arunashree ; Singh, Harkesh B. ; Butcher, Ray J. (1999) Intramolecular Se···N nonbonding interactions in low-valent organoselenium derivatives: a detailed study by 1H and 77Se NMR spectroscopy and X-ray crystallography Chemistry - A European Journal, 5 (5). pp. 1411-1421. ISSN 0947-6539

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1...

Related URL: http://dx.doi.org/10.1002/(SICI)1521-3765(19990503)5:5<1411::AID-CHEM1411>3.0.CO;2-M

Abstract

A series of novel low-valent organoselenium compounds stabilized by Se···N intramolecular interactions (such as the one in the figure) were synthesized, characterized, and examined for Se···N nonbonding interactions. A correlation between Se···N intramolecular distance and 77Se chemical shift is attempted.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Halides; Hypervalent Compounds; Intramolecular Coordination; Selenides; Selenium
ID Code:47622
Deposited On:11 Jul 2011 13:39
Last Modified:20 Jun 2012 15:35

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