Synthesis of a metallophilic metallamacrocycle: a HgII···CuI···HgII···HgII···CuI···HgII interaction

Patel, Upali ; Singh, Harkesh B. ; Wolmershäuser, Gotthelf (2005) Synthesis of a metallophilic metallamacrocycle: a HgII···CuI···HgII···HgII···CuI···HgII interaction Angewandte Chemie International Edition, 44 (11). pp. 1715-1717. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.200462487

Abstract

Complexation of a CuI ion in a mercuramacrocycle demonstrates the potential of metal-metal interactions in a preorganized system to trap metal ions. The molecular structure of the CuI complex is presented and shows Hg···Cu heterometallic and Hg···Hg homometallic d10···d10 interactions (see figure).

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Copper; Heterometallic Complexes; Mercury; Metallacycles; Metal-metal Interactions
ID Code:47619
Deposited On:11 Jul 2011 13:43
Last Modified:11 Jul 2011 13:43

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