Synthesis and characterization of some ferrocene-containing telluroether ligands: crystal structure of 1,1'-bis(phenyltelluro)ferrocene

Singh, Harkesh B. ; V., Anna Regini ; Jasinski, Jerry P. ; Paight, Ernest S. ; Butcher, Ray J. (1994) Synthesis and characterization of some ferrocene-containing telluroether ligands: crystal structure of 1,1'-bis(phenyltelluro)ferrocene Journal of Organometallic Chemistry, 464 (1). pp. 87-94. ISSN 0022-328X

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-328X(94)87014-4

Abstract

A series of five monodentate ferrocene tellurium ligands of the type Fe(C5H5)(C5H4TeR) and five bidentate 1,1'-disubstituted ferrocene tellurium ligands of the type Fe(C5H4TeR)2 (R=Me, nBu, C6H5, p-MeOC6H4, p-EtOC6H4) has been prepared by the reaction of 1,1'-dilithioferrocene with the appropriate ditellurides R2Te2. The ligands have been characterized by their elemental analyses, 1H and 13C NMR spectra, mass spectra and cyclic voltammetry studies. The structure of Fe(C5H4TeC6H5)2 has been determined by single-crystal X-ray diffraction study.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Ferrocene; Telluroether; Crystal Structure
ID Code:47599
Deposited On:11 Jul 2011 13:36
Last Modified:11 Jul 2011 13:36

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