Dithiaheterocycle-annelated tetrathiafulvalene π-donors: a structure-property correlation study

Suresh Kumar, E. V. K. ; Singh, Jai D. ; Singh, Harkesh B. ; Das, Kalyan ; Yakhmi, Jatinder V. ; Butcher, Ray J. (1998) Dithiaheterocycle-annelated tetrathiafulvalene π-donors: a structure-property correlation study Journal of the Chemical Society, Perkin Transactions 1 (11). pp. 1769-1778. ISSN 0300-922X

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1998...

Related URL: http://dx.doi.org/10.1039/A801701H

Abstract

Single-crystal X-ray structures of BEDT-TTF analogues 3, 6, 7 and 7a along with the preparation of a range of new cation-radical salts derived from these π-electron donors are reported. Physical properties (i.e. colour, cyclic voltammetry data and solid-state conductivities of the derived cation-radical salts) of the donors are discussed in terms of their crystal and molecular structures. The synthesis of compound 7 has been re-investigated. An efficient synthesis of both isomers 7 and 7a along with the other related TTF derivatives is presented. The crystal structure of the precursor thione 10 is also described.

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