Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocylces towards Pd(II) and Pt(II): Isolation and structural characterization of the first metallamacrocyle with a C-Pt-Se linkage

Panda, Snigdha ; Singh, Harkesh B. ; Butcher, Ray J. (2004) Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocylces towards Pd(II) and Pt(II): Isolation and structural characterization of the first metallamacrocyle with a C-Pt-Se linkage Chemical Communications (3). pp. 322-323. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2004...

Related URL: http://dx.doi.org/10.1039/B312358H

Abstract

Interaction of the 22-membered selenaaza macrocyle 3 with Pt(II) leads to the formation of the novel cationic Pt(IV) metallamacrocylic complex 5 via the oxidative addition of a C-Se bond to Pt(II), whereas corresponding reactions of 3 and 4 with Pd(II) afford cationic complexes 6 and 7 with differing ligating properties.

Item Type:Article
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ID Code:47563
Deposited On:11 Jul 2011 13:41
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