Menon, Saija C. ; Panda, Arunashree ; Singh, Harkesh B. ; Butcher, Ray J. (2000) Synthesis and single crystal X-ray structure of the first cationic Pd(II) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(II) and Pt(II) with a 22-membered macrocyclic Schiff base Chemical Communications (2). pp. 143-144. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2000...
Related URL: http://dx.doi.org/10.1039/A908683H
Abstract
The reaction of the tellurium containing macrocyclic Schiff base 1 with Pd(PhCN)2Cl2 and NH4PF6 gives the expected cationic complex [PdII1][PF6]2; by contrast the reaction of 1 with Pt(cod)Cl2 proceeds via novel transmetallation to yield an organoplatinum complex.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 47562 |
| Deposited On: | 11 Jul 2011 13:40 |
| Last Modified: | 11 Jul 2011 13:40 |
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