Reactions of di-o-tolyl telluride and selenide with palladium acetate: isolation of a novel palladium complex of a tellurenic acid anhydride and related trinuclear and tetranuclear palladium complexes

Chakraborty, Tapash ; Sharma, Sagar ; Singh, Harkesh B. ; Butcher, Ray J. (2011) Reactions of di-o-tolyl telluride and selenide with palladium acetate: isolation of a novel palladium complex of a tellurenic acid anhydride and related trinuclear and tetranuclear palladium complexes Organometallics, 30 (9). pp. 2525-2530. ISSN 0276-7333

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Official URL: http://pubs.acs.org/doi/abs/10.1021/om2000184

Related URL: http://dx.doi.org/10.1021/om2000184

Abstract

The reaction of di-o-tolyl telluride with palladium acetate provided a novel palladium complex of a tellurenic acid anhydride, (o-tolylTe)2OPdOAc2, and a linear trinuclear complex, [Pd(o-tolyl){di-o-tolyl telluride}]2Pd(μ-OAc)2. The reaction of di-o-tolyl selenide with palladium acetate afforded a tetranuclear complex of rare geometry, [Pd(OAc)(μ-Se-o-tolyl)]4.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:47546
Deposited On:11 Jul 2011 13:48
Last Modified:11 Jul 2011 13:48

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