Spectroscopic evidence for the removal of mobile holes on Fe doping in YBa2Cu3−xFexO7−δ

Sarma, D. D. ; Sen, P. ; Carbone, C. ; Gudat, W. (1991) Spectroscopic evidence for the removal of mobile holes on Fe doping in YBa2Cu3−xFexO7−δ Solid State Communications, 77 (5). pp. 381-383. ISSN 0038-1098

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0038-1098(91)90755-K

Abstract

X-ray absorption spectra at the oxygen K edge using the total yield technique are reported for YBa2Cu3O6.9 and YBa2Cu2.7Fe0.3O6.9. A comparison of the two spectra reveals that the mobile holes in YBa2Cu3O7−δ are removed and localized on Fe doping. Fe thus enters the lattice primarily in the formally trivalent oxidation state.

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ID Code:46406
Deposited On:04 Jul 2011 11:41
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