Pressure and alloying effects on the metal to insulator transition in NiS2−xSex studied by infrared spectroscopy

Perucchi, A. ; Marini, C. ; Valentini, M. ; Postorino, P. ; Sopracase, R. ; Dore, P. ; Hansmann, P. ; Jepsen, O. ; Sangiovanni, G. ; Toschi, A. ; Held, K. ; Topwal, D. ; Sarma, D. D. ; Lupi, S. (2009) Pressure and alloying effects on the metal to insulator transition in NiS2−xSex studied by infrared spectroscopy Physical Review B: Condensed Matter and Materials Physics, 80 (7). 073101_1-073101_4. ISSN 1098-0121

[img]
Preview
PDF - Author Version
206kB

Official URL: http://prb.aps.org/abstract/PRB/v80/i7/e073101

Related URL: http://dx.doi.org/10.1103/PhysRevB.80.073101

Abstract

The metal to insulator transition in the charge-transfer NiS2−xSex compound has been investigated through infrared reflectivity. Measurements performed by applying pressure to pure NiS2 (lattice contraction) and by Se alloying (lattice expansion) reveal that in both cases an anomalous metallic state is obtained. We find that optical results are not compatible with the linear Se-alloying vs pressure-scaling relation previously established through transport, thus pointing out the substantially different microscopic origin of the two transitions.

Item Type:Article
Source:Copyright of this article belongs to The American Physical Society.
ID Code:46381
Deposited On:04 Jul 2011 12:13
Last Modified:18 May 2016 02:17

Repository Staff Only: item control page