Separation of close boiling alcohols through selective etherification with isobutylene: use of ion exchange resins as catalyst

Jayadeokar, S. S. ; Sharma, M. M. (1993) Separation of close boiling alcohols through selective etherification with isobutylene: use of ion exchange resins as catalyst Reactive Polymers, 21 (1-2). pp. 37-43. ISSN 0923-1137

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0923-1137(93)90052-H

Abstract

A novel way for the separation of mixtures of close boiling primary + secondary and secondary + tertiary alcohols through selective etherification with isobutylene in the presence of acidic ion exchange resins as catalysts is proposed. Mixtures of ethanol + isopropanol and isopropanol + tert-butanol were used as model components. The Langmuir-Hinshelwood model was used for studying the kinetics of these reactions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Separation through Reaction; Mixed Alcohols; tert-butyl Ethers; Ion Exchange Resin Catalysts
ID Code:46208
Deposited On:02 Jul 2011 10:52
Last Modified:02 Jul 2011 10:52

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