Ladhabhoy, M. E. ; Sharma, M. M. (1969) Absorption of oxygen by n-butyraldehyde Journal of Applied Chemistry, 19 (9). pp. 267-272. ISSN 0021-8871
Full text not available from this repository.
Official URL: http://onlinelibrary.wiley.com/doi/10.1002/jctb.50...
Related URL: http://dx.doi.org/10.1002/jctb.5010190907
Abstract
The kinetics of absorption of oxygen by n-butyraldehyde dissolved in n-butyric acid, in the range of concentrations up to 3·1 × 10-3 gmole/cm3 (25 wt.-%), in the presence of manganese acetate, was studied in stirred cells and a bubble column. It was found that diffusion of oxygen is important. The reaction was found to be first-order in oxygen and second-order with respect to the aldehyde. The overall third-order reaction rate constant was found to be about 4 × 106 (cm3/gmole)2 sec-1 at 20°. The effect of the catalysts, cobaltous acetate and (cobaltous + 4 cupric) acetates, on the specific rates of absorption of oxygen was also studied. Manganese acetate was found to be the best catalyst.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 46196 |
| Deposited On: | 02 Jul 2011 10:40 |
| Last Modified: | 02 Jul 2011 10:40 |
Repository Staff Only: item control page
