Separation of close-boiling substituted phenols by anhydrous calcium hydroxide and recovery of phenols from calcium phenoxides by carbonation

Pahari, Pradip K. ; Sharma, Man Mohan (1992) Separation of close-boiling substituted phenols by anhydrous calcium hydroxide and recovery of phenols from calcium phenoxides by carbonation Industrial & Engineering Chemistry Research, 31 (8). pp. 2040-2042. ISSN 0888-5885

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ie00008a028

Related URL: http://dx.doi.org/10.1021/ie00008a028

Abstract

Separation of close-boiling phenolic mixtures of p-cresol/2,6-xylenol and o-methoxyphenol/alkylphenols has been successfully accomplished by «dissociation extraction» using solid anhydrous calcium hydroxide. Separation factors having very high values were realized. The phenols were recovered from their calcium salts by carbonation of filtered calcium salts suspended in a nonpolar organic medium.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:46169
Deposited On:02 Jul 2011 10:52
Last Modified:07 Jul 2011 04:44

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