Reactions of nitrochlorobenzenes with sodium sulfide: change in selectivity with phase-transfer catalysts

Pradhan, Narayan C. ; Sharma, Man Mohan (1992) Reactions of nitrochlorobenzenes with sodium sulfide: change in selectivity with phase-transfer catalysts Industrial & Engineering Chemistry Research, 31 (7). pp. 1606-1609. ISSN 0888-5885

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/ie00007a005

Related URL: http://dx.doi.org/10.1021/ie00007a005

Abstract

o-Nitro- and p-nitrochlorobenzene were reduced to the corresponding chloroanilines with aqueous solutions of sodium sulfide both in the presence and absence of a phase-transfer catalyst. The use of phase-transfer catalysts, with solid sodium sulfide, was found to change the course of the reaction completely to dinitrodiphenyl sulfide. The role of mass transfer in the system was assessed with m-nitrochlorobenzene as the organic substrate.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:46167
Deposited On:02 Jul 2011 10:50
Last Modified:07 Jul 2011 04:45

Repository Staff Only: item control page