Pradhan, Narayan C. ; Sharma, Man Mohan (1992) Reactions of nitrochlorobenzenes with sodium sulfide: change in selectivity with phase-transfer catalysts Industrial & Engineering Chemistry Research, 31 (7). pp. 1606-1609. ISSN 0888-5885
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/ie00007a005
Related URL: http://dx.doi.org/10.1021/ie00007a005
Abstract
o-Nitro- and p-nitrochlorobenzene were reduced to the corresponding chloroanilines with aqueous solutions of sodium sulfide both in the presence and absence of a phase-transfer catalyst. The use of phase-transfer catalysts, with solid sodium sulfide, was found to change the course of the reaction completely to dinitrodiphenyl sulfide. The role of mass transfer in the system was assessed with m-nitrochlorobenzene as the organic substrate.
Item Type: | Article |
---|---|
Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 46167 |
Deposited On: | 02 Jul 2011 10:50 |
Last Modified: | 07 Jul 2011 04:45 |
Repository Staff Only: item control page