Jayadeokar, S. S. ; Sharma, M. M. (1992) Absorption of isobutylene in aqueous ethanol and mixed alcohols: cation exchange resins as catalyst Chemical Engineering Science, 47 (13-14). pp. 3777-3784. ISSN 0009-2509
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2509(92)85097-U
Abstract
The kinetics of absorption of isobutylene in sub-azeotropic aqueous ethanol, to give ethyl-tert-butyl ether (ETBE) and tert-butanol (TBA), was investigated in a 0.075 m i.d magnetically stirred autoclave in the temperature range of 303 to 333 κ and a pressure of 0.345 MPa. The kinetics of absorption of isobutylene in mixed close boiling alcohols (ethanol + iso-propanol; iso-propanol + tert-butanol) was also investigated in the temperature range of 303 to 343 κ and a pressure of 0.345 MPa. It is possible to separate alcohols in view of large differences in rates of reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Isobutylene; Alcohols; tert-ethers; Cation Exchange Resin |
| ID Code: | 46131 |
| Deposited On: | 02 Jul 2011 07:30 |
| Last Modified: | 02 Jul 2011 07:30 |
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