4f mixing in ternary metallic cerium systems

Sampathkumaran, E. V. ; Kalkowski, G. ; Laubschat, C. ; Kaindl, G. ; Domke, M. ; Schmiester, G. ; Wortmann, G. (1985) 4f mixing in ternary metallic cerium systems Journal of Magnetism and Magnetic Materials, 47-48 . pp. 212-214. ISSN 0304-8853

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/030488...

Related URL: http://dx.doi.org/10.1016/0304-8853(85)90397-X


The results of LIII-edge X-ray absorption, bremsstrahlung-isochromat spectroscopy, and valence-band photoemission measurements are reported for the series of compounds CeX2Si2 (with X=Fe, Co, Ni). In view of the known lattice-constant anomalies of these compounds, it is concluded that the Ce-4f electrons hybridize with ligand orbitals.

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