Origin of Knight-shift anomaly in intermediate-valence compounds

Sampathkumaran, E. V. ; Stang, I. ; Vijayaraghavan, R. ; Kaindl, G. ; Lüders, K. (1985) Origin of Knight-shift anomaly in intermediate-valence compounds Physical Review B: Condensed Matter and Materials Physics, 31 (9). pp. 6099-6101. ISSN 1098-0121

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Official URL: http://prb.aps.org/abstract/PRB/v31/i9/p6099_1

Related URL: http://dx.doi.org/10.1103/PhysRevB.31.6099


A strong anomaly in the expected linear relation between 31NMR Knight shift and bulk magnetic susceptibility is observed at low temperatures for an intermediate-valence Eu-based compound, i.e., EuNi2P2. It is shown that this anomaly is not caused by crystalline-electric-field or lattice-volume effects. Instead, it is the result of the formation of the hybridized 4f conduction-electron ground state at low temperatures.

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