A dodecameric water cluster built around a cyclic quasiplanar hexameric core in an organic supramolecular complex of a cryptand

Ghosh, Sujit K. ; Bharadwaj, Parimal K. (2004) A dodecameric water cluster built around a cyclic quasiplanar hexameric core in an organic supramolecular complex of a cryptand Angewandte Chemie International Edition, 43 (27). pp. 3577-3580. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.200454002

Abstract

An infinite network is formed by the hydrogen bonding of a cluster of 12 hydrogen-bonded water molecules (see picture) to the secondary amino nitrogen atoms of a laterally nonsymmetric azacryptand. This mode of association had not previously been predicted or found experimentally.

Item Type:	Article
Source:	Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:	Cryptands; Hydrogen Bonds; Supramolecular Chemistry; Water Chemistry; X-ray Diffraction
ID Code:	4564
Deposited On:	18 Oct 2010 07:31
Last Modified:	16 May 2016 15:11

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