Sampathkumaran, E. V. ; Kaindl, G. ; Krone, W. ; Perscheid, B. ; Vijayaraghavan, R. (1985) Final-state effects in the Eu LIII-edge spectrum of EuPd2P2 Physical Review Letters, 54 (10). pp. 1067-1070. ISSN 0031-9007
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Official URL: http://prl.aps.org/abstract/PRL/v54/i10/p1067_1
Related URL: http://dx.doi.org/10.1103/PhysRevLett.54.1067
Abstract
The Eu LIII-edge X-ray-absorption spectrum of EuPd2P2 exhibits a double-peaked white-line structure typical for mixed-valent materials, while Mössbauer isomer-shift and other magnetic measurements prove the divalent ground state of this compound. This discrepancy clearly shows the possible presence of final-state configuration-interaction effects in the LIII-edge spectra of heavy-rare-earth systems, as well as a significant 4f covalent bonding, contrary to previous assumptions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The American Physical Society. |
| ID Code: | 45631 |
| Deposited On: | 29 Jun 2011 03:12 |
| Last Modified: | 29 Jun 2011 03:12 |
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