Bagchi, Biman (1987) Fractional viscosity dependence of relaxation rates and non-steady-state dynamics in barrierless reactions in solution Chemical Physics Letters, 138 (4). pp. 315-320. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(87)80390-1
Abstract
A finite decay model of barrierless electronic relaxation in solution is studied both analytically and numerically. The fractional viscosity (η) dependence of the rate (k∝η-α with 1> α > 0) is shown to be strongly correlated with non-steady-state dynamics on the reaction potential surface. We also find that the exponent a may depend strongly on the wavelength of the exciting light.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 4526 |
| Deposited On: | 18 Oct 2010 07:36 |
| Last Modified: | 18 Oct 2010 07:36 |
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