Bagchi, Biman ; Castner, Edward W. ; Fleming, Graham R. (1989) On the generalized continuum model of dipolar solvation dynamics Journal of Molecular Structure, 194 . pp. 171-181. ISSN 0022-2860
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002228...
Related URL: http://dx.doi.org/10.1016/0022-2860(89)80079-1
Abstract
The continuum model of dipolar solvation dynamics is reviewed. The effects of non-spherical molecular shapes, of non-Debye dielectric relaxation of the polar solvent and of dielectric inhomogeneity of the solvent around the solute dipole are investigated. Several new theoretical results are presented. It is found that our generalized continuum model, which takes into account the dielectric inhomogeneity of the surrounding solvent, provides a description of solvation dynamics consistent with recent experimental results.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 4513 |
| Deposited On: | 18 Oct 2010 07:38 |
| Last Modified: | 18 Oct 2010 07:38 |
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