Bagchi, Biman ; Chandra, Amalendu (1989) Solvation of an ion and of a dipole in a dipolar liquid: how different are the dynamics? Chemical Physics Letters, 155 (6). pp. 533-538. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(89)87468-8
Abstract
Theoretical expressions for the time-dependent solvation energy of an ion and of a dipole in a dense dipolar liquid are derived from microscopic considerations. We show that in contradiction to the prediction of the continuum models, the dynamics of these two species are significantly different from each other. Especially, the zero wavevector contribution, which is significant for ions, is totally absent for dipoles. Dipolar solvation may be profoundly influenced by the translational modes of the host solvent.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 4511 |
| Deposited On: | 18 Oct 2010 07:38 |
| Last Modified: | 27 Dec 2010 08:43 |
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