Synthesis and characterization of layered bismuth vanadates

Varma, K. B. R. ; Subbanna, G. N. ; Guru, T. N. ; Rao, C. N. R. (1990) Synthesis and characterization of layered bismuth vanadates Journal of Materials Research, 5 (11). pp. 2718-2722. ISSN 0884-2914

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Official URL: http://journals.cambridge.org/action/displayAbstra...

Related URL: http://dx.doi.org/10.1557/JMR.1990.2718

Abstract

Bi2VO5.5(Bi4O11), which is the vanadium analog of the first member of the Aurivillius family of oxides of the general formula Bi2An−1BnO3n+3, has been prepared and characterized. The vanadate has the expected layered structure and is ferroelectric with a Curie temperature of 720 K. While we have not been able to synthesize the vanadium analog of the n=2 member of the Aurivillius family, we have examined the structure and properties of a vanadate of the composition Bi2V3O9.

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