Bagchi, B. ; Chandra, A. ; Fleming, G. R. (1990) Dynamic solvent effects in adiabatic electron-transfer reactions: role of translational modes Journal of Physical Chemistry, 94 (13). pp. 5197-5200. ISSN 0022-3654
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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100376a001
Related URL: http://dx.doi.org/10.1021/j100376a001
Abstract
A molecular theory of the dynamic solvent effects on an outer-sphere adiabatic electron transfer reaction is presented. The theory properly includes the role of the microscopic correlations present in a dense dipolar solvent in the dynamics of an electron-transfer reaction. The theory predicts that the translational modes of the solvent, hitherto neglected in most discussions on electron-transfer reactions, can significantly enhance the rate of an adiabatic electron-transfer reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 4473 |
| Deposited On: | 18 Oct 2010 07:45 |
| Last Modified: | 27 May 2011 09:38 |
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