Kinetics and mechanism of solid-state reaction between bismuth(III) oxide and molybdenum(VI) oxide

Rastogi, R. P. ; Singh, A. K. ; Shukla, C. S. (1982) Kinetics and mechanism of solid-state reaction between bismuth(III) oxide and molybdenum(VI) oxide Journal of Solid State Chemistry, 42 (2). pp. 136-148. ISSN 0022-4596

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002245...

Related URL: http://dx.doi.org/10.1016/0022-4596(82)90260-2

Abstract

The mechanism of the following solid-state reactions between bismuth(III) oxide and molybdenum(VI) oxide was investigated within the temperature range 400-650°C.(i) Bi2O3 + MoO3→Bi2MoO6, (ii) Bi2O3 + 2MoO3→ Bi2MO2O9, (iii) Bi2O3 + 3MoO3→Bi2(MOO4)3, (iv) Bi2MoO6 + MoO3→ Bi2MO2O9, (v) Bi2Mo2O9 + MoO3 → Bi2(MoO2)3.Two types of experiments, capillary and particle size, were performed to ascertain whether MoO3 diffuses into Bi2O3 or vice versa. These show that molybdenum trioxide diffuses into bismuth oxide grains. If a is the fraction of molybdenum trioxide reacted, the kinetics in all five cases are found to be governed by the equation an = kt throughout the temperature range, where n and k are constants at a given temperature and t is the time. Both n and k are temperature dependent. The characteristic feature of these reactions is that they proceed to completion. Results are also fitted by the relation α= k2t½- k3t, where k2 and k3 are constants, which shows that the reactions occur by bulk diffusion through grain boundary contacts. The number of grain boundary contact points decreases with time in the course of reaction.

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