Zhou, Huan-Xiang ; Bagchi, Biman
(1992)
*Dielectric and orientational relaxation in a brownian dipolar lattice*
Journal of Chemical Physics, 97
(5).
pp. 3610-3620.
ISSN 0021-9606

Full text not available from this repository.

Official URL: http://link.aip.org/link/?JCPSA6/97/3610/1

Related URL: http://dx.doi.org/10.1063/1.462944

## Abstract

In this article, both numerical and analytical studies of dielectric and orientational relaxation in a simple model system are presented. The system consists of point dipoles fixed at the sites of a simple cubic lattice. The dipoles are free to undergo rotational Brownian motion in the force field of all the other dipoles of the system. The dynamics in this simple model is described essentially by only one parameter η = 1/3ρμ^{2}/k_{BT}, where ρ is the number density, μ is the dipole moment, and k_{BT} is the Boltzmann constant times the temperature. Extensive Brownian dynamics simulations are carried out to obtain the frequency-dependent dielectric function of this system. The dielectric function becomes progressively non-Debye as the polarity of the system is increased. A comparison between single particle and collective moment-moment time correlation functions is made. It is found that at high polarities, the collective correlation function decays much faster than the single particle function, although a slowly decaying component develops for the collective function. The projection operator technique is used to derive a perturbative equation of motion for the dipole moment at any lattice site-the equation is exact to the second order in η. This approach is quite successful in explaining the single particle dynamics. The perturbative equation also accounts for the progressively faster initial decay of the collective correlation function as η increases. However, it fails to describe the slowly decaying component and consequently the observed non-Debye behavior at large η. We also make a detailed comparison of the simulation results with the self-consistent continuum model of Nee and Zwanzig. It is found that the generalized diffusion equation is reliable if an accurate dielectric friction is used (from simulation, for example). However, the other ingredients of the continuum model are inadequate to describe the dielectric relaxation in this system. In particular, the predicted torque-torque correlation function decays too rapidly compared to the simulation results.

Item Type: | Article |
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Source: | Copyright of this article belongs to American Institute of Physics. |

ID Code: | 4437 |

Deposited On: | 18 Oct 2010 07:53 |

Last Modified: | 10 Jan 2011 08:12 |

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