State-resolved scattering of molecules in pendular states: ICl+Ar

Friedrich, B. ; Rubahn, H. -G. ; Sathyamurthy, N. (1992) State-resolved scattering of molecules in pendular states: ICl+Ar Physical Review Letters, 69 (17). pp. 2487-2490. ISSN 0031-9007

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Official URL: http://prl.aps.org/abstract/PRL/v69/i17/p2487_1

Related URL: http://dx.doi.org/10.1103/PhysRevLett.69.2487

Abstract

The effect of pendular orientation of the figure axis of ICl on elastic and inelastic scattering by Ar was explored in a crossed beam experiment. The pendular states of ICl are created by hybridizing its rotational states up to J≤3 in a uniform electric field of strength E=100 kV/cm. The resulting change in the distribution of individual J states of ICl is measured state-selectively by laser-induced fluorescence near the zero scattering angle outside the field. We find that the electric field inhibits rotationally inelastic scattering of low-J state molecules, due to a larger spacing between levels.

Item Type:Article
Source:Copyright of this article belongs to The American Physical Society.
ID Code:43938
Deposited On:17 Jun 2011 13:47
Last Modified:17 Jun 2011 13:47

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