An interesting isotope effect in the Raman excitation profile for HI

Chakrabarti, N. ; Sathyamurthy, N. (1998) An interesting isotope effect in the Raman excitation profile for HI Journal of Physical Chemistry A, 102 (36). pp. 7089-7092. ISSN 1089-5639

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp982104q

Related URL: http://dx.doi.org/10.1021/jp982104q

Abstract

It is shown that the Raman excitation profile for the fundamental Stokes transition of DI in the vicinity of its electronic transition to the nearby dissociative states exhibits a larger deenhancement than that for HI, as a result of larger interference between the resonance Raman amplitudes for the four closely lying excited (dissociative) electronic states.

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