Chakrabarti, N. ; Balasubramanian, V. ; Sathyamurthy, N. ; Gadzuk, J. W. (1995) Photoinduced desorption in NO/Pt: a time-dependent quantum mechanical study Chemical Physics Letters, 242 (4-5). pp. 490-498. ISSN 0009-2614
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2614(95)00749-T
Abstract
We have carried out a TDQM study of photoinduced desorption in NO/Pt by involving hot electron transfer and allowing different residence times (τR) on the excited state potential-energy surface. The desorption probability (Pdes) is dependent on τR, but it is clear from the results that the substantial Pdes can be accounted for by assuming τR is in the range 20-60 fs. The study also accounts for vibrational excitation in the desorbed NO.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 43856 |
| Deposited On: | 17 Jun 2011 05:31 |
| Last Modified: | 17 Jun 2011 05:31 |
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