On the validity of the power gap law for rotational energy transfer in CO2-H2 collisions

Noor Batcha, I. ; Sathyamurthy, N. (1981) On the validity of the power gap law for rotational energy transfer in CO2-H2 collisions Chemical Physics Letters, 79 (2). pp. 264-268. ISSN 0009-2614

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0009-2614(81)80201-1

Abstract

The validity of the power gap law for rotational energy transfer has been tested in the case of rigid-roior CO2-H2 collisions The power law with a single parameter γ is shown to be adequate only for small amounts of energy transferred. For larger amounts, use of a different γ seems to be warranted suggesting a deficiency of the power iaw or operation of two mechanisms for rotational energy transfer.

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Deposited On:16 Jun 2011 11:48
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