Jayaraman, Krishnamoorthy ; Choudhury, Amitava ; Vaidhyanathan, Ramanathan ; Rao, C. N. R. (2001) A layered chlorophosphate, Na3[Cd4Cl3(HPO4)2(H2PO4)4], containing Na+ ions in the interlamellar space New Journal of Chemistry, 25 (9). pp. 1199-1202. ISSN 1144-0546
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2001...
Related URL: http://dx.doi.org/10.1039/B103278J
Abstract
Reaction between CdCl2·H2O and NaH2PO4·H2O under hydrothermal conditions gives rise to a new cadmium chlorophosphate of the formula Na3[Cd4Cl3(HPO4)2(H2PO4)4], I. This material crystallizes in the orthorhombic system with space group Fmm2 (no. 42). I has macroanionic layers of [Cd4Cl3(HPO4)2(H2PO4)4]3− with Na+ ions in the interlamellar space. The discovery of such compounds suggests that metathetic reactions carried out under hydrothermal conditions may provide a novel route for the synthesis of new open-framework structures.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 43738 |
| Deposited On: | 15 Jun 2011 06:39 |
| Last Modified: | 18 May 2016 00:38 |
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