Dipole moments and charge-transfer parameters of the iodine complexes of some oxygen and sulfur donors

Bhat, S. N. ; Rao, C. N. R. (1968) Dipole moments and charge-transfer parameters of the iodine complexes of some oxygen and sulfur donors Journal of the American Chemical Society, 90 (22). pp. 6008-6010. ISSN 0002-7863

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/ja01024a012

Related URL: http://dx.doi.org/10.1021/ja01024a012

Abstract

Dipole moments of the charge-transfer complexes of some sulfur (sulfide and thiocarbonyl) and oxygen (ether and carbonyl) donors with iodine have been determined and the various charge-transfer parameters have been calculated by making use of the charge-transfer transition energies and heats of formation of the complexes. The contribution of the charge-transfer structure in the ground state appears to be greater in the complexes of sulfur donors than in the complexes of oxygen donors.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:43467
Deposited On:11 Jun 2011 13:30
Last Modified:11 Jun 2011 13:30

Repository Staff Only: item control page