Kaliyamurthy, K. ; Elayaperumal, P. ; Balakrishnan, T. ; Santappa, M. (1982) Kinetics of polymerization of vinyl monomers initiated by manganese(III) acetate. I Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 18 (2). pp. 219-236. ISSN 1060-1325
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Related URL: http://dx.doi.org/10.1080/00222338208074420
Abstract
The kinetics of thermal polymerization of acrylic acid (AA), methacrylic acid (MAA), acrylonitrile (AN), and methacryl-amide (MAM) in aqueous sulfuric acid using manganic acetate was studied. The effect of variations in [monomer], [Mn3+], [H+], μ, and temperature on the rates of monomer disappearance (Rp), Mn3+ disappearance (−Rm), and the degree of polymerization (Xn) were studied. Based on the kinetic results, a suitable reaction scheme is proposed and rate expressions are derived. The rate constants, such as ki, kp/kt, and thermo-dynamic parameters, corresponding to these are evaluated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Group. |
| ID Code: | 43404 |
| Deposited On: | 11 Jun 2011 10:57 |
| Last Modified: | 11 Jun 2011 10:57 |
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