Oxidation studies. IV. Kinetics of oxidation of HCHO and some alcohols by ceric salts in HNO3 medium

Santappa, M. ; Sethuram, B. (1968) Oxidation studies. IV. Kinetics of oxidation of HCHO and some alcohols by ceric salts in HNO3 medium Proceedings of the Indian Academy of Sciences, Section A, 67 (2). pp. 78-89. ISSN 0370-0089

[img]
Preview
PDF - Publisher Version
1MB

Official URL: http://www.ias.ac.in/j_archive/proca/67/2/78-89/vi...

Related URL: http://dx.doi.org/10.1007/BF03049835

Abstract

The results on the kinetics of oxidation of HCHO and some alcohols,viz., n-propanol, allyl alcohol, cyclohexanol and benzyl alcohol by ceric nitrate in nitric acid medium in the temperature range of 10-35° C. are presented. The active form of Ce4+ during the oxidation of the above organic substrates was assumed to be the neutral Ce(NO3)4. The mechanism of oxidation and thermodynamic parameters for the above compounds are also given.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
ID Code:43385
Deposited On:11 Jun 2011 09:53
Last Modified:18 May 2016 00:24

Repository Staff Only: item control page