Ion solvation dynamics in supercritical water

Biswas, Ranjit ; Bagchi, Biman (1998) Ion solvation dynamics in supercritical water Chemical Physics Letters, 290 (1-3). pp. 223-228. ISSN 0009-2614

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A theoretical study of ionic solvation dynamics in supercritical water is presented. The short-time decay of the calculated equilibrium solvation energy time correlation function (SE(t)) is found to be in good agreement with the recent computer simulation results. The simulated long-time decay is, however, somewhat slower than that which is predicted by the present theory. Two plausible molecular explanations for the slow long-time decay of SE(t) are offered.

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Source:Copyright of this article belongs to Elsevier Science.
ID Code:4302
Deposited On:13 Oct 2010 09:51
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