Molecular oxygen insertion into picolyl, thenyl, furyl and furfuryl cobaloximes under thermal and photochemical conditions and their decomposition studies

Gupta, B. D. ; Roy, Sujit (1985) Molecular oxygen insertion into picolyl, thenyl, furyl and furfuryl cobaloximes under thermal and photochemical conditions and their decomposition studies Inorganica Chimica Acta, 108 (4). pp. 261-264. ISSN 0020-1693

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0020-1693(00)81290-6

Abstract

Some new picolyl, thenyl, furyl and furfuryl cobaloximes have been synthesized. The insertion of molecular oxygen into the Co---C bond occurs readily under photochemical stimulation but there is no insertion under heating. The thermal decomposition of the inserted product in benzene and methanol forms aldehydes and alcohols.

Item Type:Article
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ID Code:42960
Deposited On:08 Jun 2011 12:15
Last Modified:08 Jun 2011 12:15

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