Gupta, B. D. ; Roy, Sujit ; Roy, Maheswar (1987) Sulphur dioxide insertion into organocobaloximes: a true insertion of a case of radical chain process! Tetrahedron Letters, 28 (11). pp. 1219-1222. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)95330-9
Abstract
The insertion of sulphur dioxide into Co---C bond of organocobaloximes, RCoIII (dmgH)2Py (R=2- and 3-thienyl methyl, furfuryl and 3-furyl) occurs readily under photochemical stimulations at 0°C, but there is no insertion under thermal conditions. The reactions are not true insertions but occur by a radical chain process.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 42959 |
| Deposited On: | 08 Jun 2011 11:58 |
| Last Modified: | 08 Jun 2011 12:47 |
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