Kundu, Abhijit ; Prabhakar, Sripadi ; Vairamani, M. ; Roy, Sujit (1999) A novel copper(II)/tin(II) reagent for regio- and chemoselective carbonyl propargylation Organometallics, 18 (15). pp. 2782-2785. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om9900317
Related URL: http://dx.doi.org/10.1021/om9900317
Abstract
A convenient and synthetically attractive protocol for the regioselective synthesis of homopropargyl alcohols from aldehydes and 2-propynyl halides having terminal alkynes under the aegis of catalytic cupric bromide and stannous chloride in THF is described. In-situ probing by 1H NMR and MIKE-CID spectrum provides evidence for the copper(I)-catalyzed formation of allenyltrihalostannane.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 42904 |
| Deposited On: | 08 Jun 2011 06:25 |
| Last Modified: | 08 Jun 2011 06:25 |
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