Binding of amino acids into a novel multiresponsive ferrocene receptor having an ene backbone

Debroy, Paromita ; Banerjee, Moloy ; Prasad, Madhumita ; Moulik, Satya P. ; Roy, Sujit (2005) Binding of amino acids into a novel multiresponsive ferrocene receptor having an ene backbone Organic Letters, 7 (3). pp. 403-406. ISSN 1523-7060

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/ol0476772

Related URL: http://dx.doi.org/10.1021/ol0476772

Abstract

Receptor 1 featuring two open arms, multipoint binding sites, and unsaturated linkers on a ferrocene platform shows strong 1:1 binding to unprotected α-amino acids (UV-vis, fluorescence, CV, ITC, NMR, and ESI-MS). NMR and ESI-MS studies suggest an encapsulative binding mode involving the α,β-unsaturated carbonyl residue (site for -NH3+, interaction A) and the terminal -OH groups (site for -COO, interaction B).

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:42902
Deposited On:08 Jun 2011 06:22
Last Modified:08 Jun 2011 06:22

Repository Staff Only: item control page