Das, Jaya Prakash ; Sinha, Pradipta ; Roy, Sujit (2002) A nitro-Hunsdiecker reaction: from unsaturated carboxylic acids to nitrostyrenes and nitroarenes Organic Letters, 4 (18). pp. 3055-3058. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol0262901
Related URL: http://dx.doi.org/10.1021/ol0262901
Abstract
The nitrodecarboxylation of aromatic α,β-unsaturated carboxylic acids and ring-activated benzoic acids can be achieved using nitric acid (3 equiv) and catalytic AIBN (2 mol %) in MeCN. From the effect of various additives, the nitrodecarboxylation is postulated to involve the generation of an acyloxy radical RCO2· by a NO3· radical followed by attack of a NO2· radical.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 42901 |
| Deposited On: | 08 Jun 2011 06:20 |
| Last Modified: | 08 Jun 2011 06:20 |
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