An organically templated open-framework cobalt germanate

Julius, Njapba Ngu ; Choudhury, Amitava ; Rao, C. N. R. (2003) An organically templated open-framework cobalt germanate Journal of Solid State Chemistry, 170 (1). pp. 124-129. ISSN 0022-4596

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0022-4596(02)00048-8

Abstract

An open-framework cobalt germanate of the formula, [Co2(NH2(CH2)2NH2)3][Ge9O18(OH)4] has been prepared under solvo/hydrothermal conditions in the presence of ethylenediamine. The germanate is constructed by Ge9O18 clusters and contains eight- and ten-membered channels. Besides connecting two Co sites, the amine also acts as a bis-chelating agent and protrudes into the eight-membered channel.

Item Type:Article
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ID Code:42416
Deposited On:02 Jun 2011 13:38
Last Modified:02 Jun 2011 13:38

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