Pasha, Intyaj ; Choudhury, Amitava ; Rao, C. N. R. (2003) The first organically templated linear metal selenate Journal of Solid State Chemistry, 174 (2). pp. 386-391. ISSN 0022-4596
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00224...
Related URL: http://dx.doi.org/10.1016/S0022-4596(03)00256-1
Abstract
An organically templated cadmium selenate of the formula [enH2][Cd(H2O)2(SeO4)2], I, has been synthesized by carrying out the reaction between CdO and H2SeO4 in the presence of the amine in aqueous medium at 80°C. The structure of I involves isolated infinite [Cd(H2O)2(SeO4)2]2− chains running along the c-axis, with the protonated ethylenediamine molecules between them. Crystal data for I are as follows: Monoclinic, space group=C2/c, a=10.5059(7), b=10.3605(7), c=10.6028(7)Å, β=94.666(2)°, V=1150.25(13)Å3, z=8, R1=0.0237, wR2=0.0500 (for all data).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cadmium Selenate; Organically Templated Material; One-dimensional Structure; Kröhnkite-type Chain and Thermogravimetric Analysis |
| ID Code: | 42390 |
| Deposited On: | 02 Jun 2011 12:56 |
| Last Modified: | 02 Jun 2011 12:56 |
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